反応 #5382

反応方程式

diglycidyl ether of bisphenol A

methyl isobutyl ketone

triphenylphosphine

→

resorcinol ether

反応条件

後処理

1. 1
   その他was prepared in a lab reactor by a procedure comparable to
2. 2
   workup.ADDITIONThe reactor was charged with about 31.1 g

実験手順

A resorcinol-formaldehyde resin/diglycidyl ether of bisphenol A addition product was prepared in a lab reactor by a procedure comparable to that employed in Example 1. The reactor was charged with about 31.1 g. of a commercial resorcinol-formaldehyde resin, Penacolite B-19-S, (INDSPEC Chemical Corporation, Pittsburgh, Pa., U.S.A.), 125 ml methyl isobutyl ketone and 0.5 g. triphenylphosphine. Then, 90.4 g diglycidyl ether of bisphenol A (Dow epoxy resin DER-331) was added dropwise in about 0.5 hours. The stirred solution was refluxed for about one hour at about 117° C. and devolatilized at reduced pressure to give a dark amber resorcinol ether compound (RE2) having a 72° C. softening point, and having a 0.9 wt. % residual oxirane oxygen.

出典