反応 #5319

反応方程式

sodium hydroxide

dimethyllaurylbenzylammonium chloride

1,1-bis(chlorophenyl)-2,2,2-trichloroethane

→

1,1-bis(chlorophenyl)-2,2-dichloroethylene

収率 97.8%

溶媒

monochlorobenzene

反応条件

後処理

1. 1
   温度The mixture was heated
2. 2
   その他The organic phase was separated by phase separation
3. 3
   洗浄was washed three times with 100 g of water
4. 4
   workup.DISTILLATIONAfter distillation of the monochlorobenzene

実験手順

201.5 g of 28% strength aqueous sodium hydroxide and 2.0 g of dimethyllaurylbenzylammonium chloride were added to a solution of 250 g of 1,1-bis(chlorophenyl)-2,2,2-trichloroethane in 100 g of monochlorobenzene at 50° C. The mixture was heated at reflux (90° C.) for 20 hours. The organic phase was separated by phase separation and was washed three times with 100 g of water. After distillation of the monochlorobenzene, 219.3 g of 1,1-bis(chlorophenyl)-2,2-dichloroethylene were obtained (y=97.8%) with 0.10% of 1,1-bis(chlorophenyl)-2,2,2-trichloroethane.

出典