反応 #531805

反応方程式

tris(3-(tert-butoxycarbonylamino)propyl)nitromethane

Tris(3-(tertbutoxycarbonylamino)propyl)nitromethane

trifluoroacetic acid

→

title compound 10c

収率 100.0%

Tris(3-aminopropyl)nitromethane trifluoroacetate salt

収率 100.0%

溶媒

dichloromethane

反応条件

後処理

1. 1
   濃縮The reaction was then concentrated under high vacuum

実験手順

A mixture of tris(3-(tert-butoxycarbonylamino)propyl)nitromethane 1c (10 g, 18.8 mmol) in trifluoroacetic acid (20 ml) and dichloromethane (50 ml) was stirred at room temperature for 4 h. The reaction was then concentrated under high vacuum to afford the title compound 10c (10.8 g, 18.8 mmol. 100%) as a gum.

出典