反応 #53079

ord-3e5d2401b98d4edba65671d88f44fe5d

反応方程式

COC(=C1C(=O)N(C(C)=O)c2ccc([N+](=O)[O-])cc21)c1ccccc1
1-acetyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone
Nc1ccc([N+](=O)[O-])cc1
4-nitroaniline
N
ammonia
→
O=C1Nc2ccc([N+](=O)[O-])cc2/C1=C(/Nc1ccc([N+](=O)[O-])cc1)c1ccccc1
(Z)-3-[1-(4-nitrophenylamino)-1-phenyl-methylidene]-5-nitro-2-indolinone

反応物

COC(=C1C(=O)N(C(C)=O)c2ccc([N+](=O)[O-])cc21)c1ccccc1
1-acetyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone
Nc1ccc([N+](=O)[O-])cc1
4-nitroaniline
N
ammonia

試薬

なし

溶媒

CN(C)C=O
DMF

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Prepared analogously to Example 77 from 1-acetyl-3-(1-methoxy-1-phenyl-methylidene)-5-nitro-2-indolinone and 4-nitroaniline in DMF and subsequent treatment with methanolic ammonia.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US06855710B2uspto-grants-2005_02