反応 #52110

ord-c62d3ce4d7174d1fad0761d7168f165f

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    温度an attached reflux condenser

実験手順

2 mmol of N-hydroxyphthalimide and 4 mmol of cumene hydroperoxide are added at a temperature of 130° C. to 200 mmol of cyclooctane in a round-bottomed flask having an attached reflux condenser. Oxygen at approximately 15 l/h is passed through the reaction mixture for 8 hours at said temperature. Cyclooctanol is obtained at a selectivity of 17% and cyclooctanone at a selectivity of 46%, at a cyclooctcane conversion rate of 53%.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US06852893B2uspto-grants-2005_02