反応 #497334

ord-cb2b44e7a7ec4a65811e4a087ff4b41b

反応方程式

O=C(O)CCCCC(=O)O
adipic acid
OCCCCCCO
1,6-hexanediol
OC1CCCCC1
cyclohexanol
O=C1CCCCC1
cyclohexanone

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Instead of pure adipic acid, dicarboxylic acid solution (DCS) has also been used as a starting material for the preparation of 1,6-hexanediol. It is obtained as a waste product in the oxidation of cyclohexane with air to give cyclohexanone and cyclohexanol, by extraction of the oxidized mixture with water.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08759594B2uspto-grants-2014_06