反応 #487527

ord-63837604956d4726a6cfde2531fe8fe5

反応方程式

CCCCCCCC/C=C\CCCCCCCC(=O)Cl
Oleoyl chloride
CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O
Erucic acid
CCCCCCCCC=CCCCCCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC
Compound D
収率 94.5%
CCCCCCCCC=CCCCCCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC
Octadec-9-enoic acid docos-13-enyl ester
収率 94.5%

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Compound D was prepared from Oleoyl chloride and Erucic acid following the general procedure discussed before and as shown in FIG. 9. Pure compound D was a colorless oil obtained by column chromatography with Ethyl acetate/Hexane=1:40. Reaction conditions for branched derivative compounds D2, D3, and D4 are also shown below.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08741822B2uspto-grants-2014_06