反応 #485986

反応方程式

Ammonia

N-[4-chloro-3-(2-chloro-2-ethoxycarbonylethenyl)-phenyl]-3,4,5,6-tetrahydrophthalimide

→

N-[4-Chloro-3-(2-chloro-2-ethoxycarbonylethenyl)-phenyl]-3,4,5,6-tetrahydrophthalamide

溶媒

acetonitrile

反応条件

後処理

1. 1
   その他The reaction mixture obtained
2. 2
   その他after which the solid formed
3. 3
   その他was separated off
4. 4
   洗浄washed with petroleum ether

実験手順

Ammonia gas was passed into a solution of 5.9 g of N-[4-chloro-3-(2-chloro-2-ethoxycarbonylethenyl)-phenyl]-3,4,5,6-tetrahydrophthalimide in 150 ml of acetonitrile until saturation was reached. The reaction mixture obtained was then stirred for a further 19 hours at 20°-25° C., after which the solid formed was separated off and then washed with petroleum ether. Mp.: 185°-186° C.

出典