反応 #4812

ord-538b2fa95db549c3b201e8be5d8840ea

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他to react at room temperature overnite
  2. 2
    その他Recrystallization from ethanol

実験手順

Benzoyl chloride 3.0 g (0.021 mol) and 1.69 g (0.021 mol) pyridine were mixed together under nitrogen and allowed to react at room temperature overnite. Benzaldehyde 2.23 g (0.021 mol) was added and the mixture was allowed to stand at ambient temperature for 4 days. Recrystallization from ethanol:ether gave 4.27 g (0.013 mol), 62%, α-benzoyloxybenzylpyridinium chloride, mp 174.5°-176.5°.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04727151uspto-grants-1988_02