反応 #477021

ord-916d5396b09e4b739a37a428a6b3c3a7

反応方程式

O=C([O-])CCCO
4-hydroxybutyrate
CC(O)CC(=O)[O-]
3-hydroxybutyrate
CC1(C)S[C@@H]2[C@H](NC(=O)[C@H](N)c3ccccc3)C(=O)N2[C@H]1C(=O)O
ampicillin
O=C(N[C@H](CO)[C@H](O)c1ccc([N+](=O)[O-])cc1)C(Cl)Cl
chloramphenicol
O=C([O-])CCCO
4-HB
CC1(C)S[C@@H]2[C@H](NC(=O)[C@H](N)c3ccccc3)C(=O)N2[C@H]1C(=O)O
ampicillin
O=C(N[C@H](CO)[C@H](O)c1ccc([N+](=O)[O-])cc1)C(Cl)Cl
chloramphenicol
→
CC(O)C(=O)[O-].CC(O)CC(=O)[O-].O=C([O-])CCCO
3-Hydroxybutyrate 4-hydroxybutyrate lactate

反応物

O=C([O-])CCCO
4-hydroxybutyrate
CC(O)CC(=O)[O-]
3-hydroxybutyrate
CC1(C)S[C@@H]2[C@H](NC(=O)[C@H](N)c3ccccc3)C(=O)N2[C@H]1C(=O)O
ampicillin
O=C(N[C@H](CO)[C@H](O)c1ccc([N+](=O)[O-])cc1)C(Cl)Cl
chloramphenicol
O=C([O-])CCCO
4-HB
CC1(C)S[C@@H]2[C@H](NC(=O)[C@H](N)c3ccccc3)C(=O)N2[C@H]1C(=O)O
ampicillin
O=C(N[C@H](CO)[C@H](O)c1ccc([N+](=O)[O-])cc1)C(Cl)Cl
chloramphenicol

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

3-Hydroxybutyrate-4-hydroxybutyrate-lactate terpolymer was prepared according to the method of example 2 except that the collected cells was anaerobically cultured for 3 days in MR medium further containing 2 g/L of 4-hydroxybutyrate (4-HB), 1 g/L of 3-hydroxybutyrate (3-HB), 100 mg/L of ampicillin and 30 mg/L of chloramphenicol instead of MR medium further containing g/L of 4-HB, 100 mg/L of ampicillin and 30 mg/L of chloramphenicol.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08383379B2uspto-grants-2013_02