反応 #460127
ord-4bb6ecef8ce947c0a9f2a7776e14e54b
反応方程式
norbornene
O2
→
norbornanone
収率 70.0%
cyclohexene carboxaldehyde
収率 30.0%
試薬
なし
反応条件
詳細条件
See reaction.notes.procedure_details.
実験手順
7.1 g norbornene and 1 atm O2 were passed over 100 mg of this material at 280° C. for 2 hours, yielding in a partial conversion 99 mg norbornanone (relative yield 70%) and 43 mg cyclohexene carboxaldehyde (relative yield 30%) with a turnover frequency of 160 moles total product per mole Rh per hr.