反応 #460127

ord-4bb6ecef8ce947c0a9f2a7776e14e54b

反応方程式

C1=CC2CCC1C2
norbornene
O=O
O2
O=C1CC2CCC1C2
norbornanone
収率 70.0%
O=CC1=CCCCC1
cyclohexene carboxaldehyde
収率 30.0%

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

7.1 g norbornene and 1 atm O2 were passed over 100 mg of this material at 280° C. for 2 hours, yielding in a partial conversion 99 mg norbornanone (relative yield 70%) and 43 mg cyclohexene carboxaldehyde (relative yield 30%) with a turnover frequency of 160 moles total product per mole Rh per hr.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05162285uspto-grants-1992_11