反応 #449985

ord-caac113d746544c498d247879c7ac4ef

反応方程式

CC(=O)c1ccc(NC(=O)CO[C@H]2CC[C@H]3[C@@H]4CC[C@H]5NC(=O)CC[C@]5(C)[C@H]4CC[C@]23C)cc1
5α-4-azaandrostan-3-on-17β-yloxy-N-(4-acetylphenyl)acetamide
C[C@]12CCC(=O)N[C@@H]1CC[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](OCC(=O)OC(c3ccccc3)c3ccccc3)CC[C@@H]12
diphenylmethyl 5α-4-azaandrostan-3-on-17β-yloxyacetate
→
C[C@]12CCC(=O)N[C@@H]1CC[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](OCC(=O)Nc3ccccc3)CC[C@@H]12
5α-4-azaandrostan-3-on-17β-yloxy-N-phenylacetamide

反応物

CC(=O)c1ccc(NC(=O)CO[C@H]2CC[C@H]3[C@@H]4CC[C@H]5NC(=O)CC[C@]5(C)[C@H]4CC[C@]23C)cc1
5α-4-azaandrostan-3-on-17β-yloxy-N-(4-acetylphenyl)acetamide
C[C@]12CCC(=O)N[C@@H]1CC[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](OCC(=O)OC(c3ccccc3)c3ccccc3)CC[C@@H]12
diphenylmethyl 5α-4-azaandrostan-3-on-17β-yloxyacetate

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

5α-4-azaandrostan-3-on-17β-yloxy-N-(4-acetylphenyl)acetamide, diphenylmethyl 5α-4-azaandrostan-3-on-17β-yloxyacetate;

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05872126uspto-grants-1999_02