反応 #43989

反応方程式

2-(2,3,4,5-tetramethylcyclopentadienyl)benzaldehyde

pentafluorophenylhydrazine

→

2-(2,3,4,5-tetramethylcyclopentadienyl)benzaldehyde pentafluorophenylhydrazone

収率 98.4%

溶媒

ethanol

反応条件

後処理

1. 1
   workup.DISTILLATIONThe solvent was distilled off under reduced pressure
2. 2
   その他the residue was recrystallized from hexane

実験手順

To a solution of 2-(2,3,4,5-tetramethylcyclopentadienyl)benzaldehyde (10.0 mmol) in ethanol (60.0 mL) was added dropwise pentafluorophenylhydrazine (11.0 mmol) under a nitrogen atmosphere. The mixture was stirred at room temperature for 2 hrs. The solvent was distilled off under reduced pressure and the residue was recrystallized from hexane to give 2-(2,3,4,5-tetramethylcyclopentadienyl)benzaldehyde pentafluorophenylhydrazone (4.00 g, yield 97.0%).

出典