反応 #4341

反応方程式

phosgene

2-[2-(2-methylthioethoxy)-phenyl]-hydrazinecarboxylic acid methyl ester

→

2-(chlorocarbonyl)-2-[2-(2-methylthioethoxy)-phenyl]-hydrazinecarboxylic acid methyl ester

溶媒

toluene

toluene

反応条件

後処理

1. 1
   その他the solvent is then removed
2. 2
   その他Recrystallisation of the residue in ethyl alcohol
3. 3
   その他yields the compound No

実験手順

80 ml of a 20% solution of phosgene in toluene are added at 20° C. to 14.1 g of 2-[2-(2-methylthioethoxy)-phenyl]-hydrazinecarboxylic acid methyl ester in 130 ml of toluene. The reaction mixture is subsequently heated for 3 hours at 90° C., and the solvent is then removed. Recrystallisation of the residue in ethyl alcohol yields the compound No. 1.1 of the formula ##STR63## having a melting point of 55°-57° C.

出典