反応 #4235

反応方程式

2-ethylbenzenesulfonyl chloride

dichlorine monoxide

→

colorless oil

収率 83.9%

2-(1-Chloroethyl)benzenesulfonyl chloride

収率 83.9%

溶媒

carbon tetrachloride

carbon tetrachloride

反応条件

後処理

1. 1
   温度the mixture was heated in a closed system at 50°-60° for 16 hrs
2. 2
   乾燥The mixture was dried (MgSO4) and volatiles
3. 3
   その他were removed under vacuum
4. 4
   workup.DISTILLATIONThe residue was kugelrohr distilled

実験手順

A solution of 2-ethylbenzenesulfonyl chloride (obtained by chlorosulfonation of ethylbenzene) (7.78 g) in carbon tetrachloride (5.0 ml) was contacted with a solution of dichlorine monoxide (82 mmol) in carbon tetrachloride (100 ml) and the mixture was heated in a closed system at 50°-60° for 16 hrs. The mixture was dried (MgSO4) and volatiles were removed under vacuum. The residue was kugelrohr distilled to give 7.63 g of colorless oil, bp 75°-80° (0.15 mm). 1H nmr δCDCl3TMS 8.20-7.35 (m). 6.13 (q, J=7 Hz), 1.90 (d, J=7 Hz).

出典