反応 #4000
ord-1df2989375bc46478b5ee78beb16d265
反応条件
詳細条件
See reaction.notes.procedure_details.
後処理
- 1その他The n-butylbenzene product is recovered
- 2温度by cooling the reaction mixture
- 3抽出extracting the resulting mixture with toluene
- 4その他The n-butylbenzene product is removed from the toluene solvent
- 5workup.DISTILLATIONby distilling the solvent
実験手順
Normal-butylbenzene is prepared by heating equal molar amounts of 1-chlorobutane and benzene in a molten urea-sulfuric acid component containing 42.6 weight percent urea and 75.4 weight percent sulfuric acid having a urea/sulfuric acid molar ratio of 1.2 at a temperature of 140° F. and a pressure of 100 psig. for a period of 10 minutes. The n-butylbenzene product is recovered by cooling the reaction mixture to solidify the urea-sulfuric acid component melt and extracting the resulting mixture with toluene. The n-butylbenzene product is removed from the toluene solvent by distilling the solvent, and the urea-sulfuric acid component is re-melted and recycled to the process.