反応 #3942

ord-111c8594f1d44a3f8495a7a4086c6573

反応方程式

CCCCCCN=C=O
n-hexyl isocyanate
SCCCN1CCCN(Cc2ccc(Cl)cc2)CC1
3-[4-(4-chlorobenzyl)homopiperazin-1-yl]propanethiol
CCCCCCNC(O)=[SH]CCCN1CCCN(Cc2ccc(Cl)cc2)CC1.Cl.Cl
N-(n-hexyl)-S-{3-[4-(4-chlorobenzyl)homopiperazin-1-yl]propyl}thiocarbamate dihydrochloride
収率 77.6%

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

The procedure described in Example 2 was followed, using 1.3 g of n-hexyl isocyanate, 3.0 g of 3-[4-(4-chlorobenzyl)homopiperazin-1-yl]propanethiol and 75 ml of methylene chloride, to give 1.3 g (33% of theory) of N-(n-hexyl)-S-{3-[4-(4-chlorobenzyl)homopiperazin-1-yl]propyl}thiocarbamate dihydrochloride as a tan powder, M.p. 183°-187° C.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04722926uspto-grants-1988_02