反応 #3936

ord-79c508329b5d4f1d8bd9e814f1079ea1

反応方程式

CCCCCCN=C=O
n-hexyl isocyanate
SCCCN1CCN(CCCCc2ccc(Cl)cc2)CC1
3-{4-[4-(4-chlorophenyl)butyl]piperazin-1-yl}propanethiol
CCCCCCNC(O)=[SH]CCCN1CCN(CCCCc2ccc(Cl)cc2)CC1.Cl.Cl
N-(n-hexyl)-S-{3-[4-[4-(4-chlorophenyl)butyl]piperazin-1-yl]propyl}thiocarbamate dihydrochloride
収率 99.8%

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

The procedure described in Example 2 was followed, using 1.0 g of n-hexyl isocyanate, 2.6 g of 3-{4-[4-(4-chlorophenyl)butyl]piperazin-1-yl}propanethiol and 25 ml of methylene chloride, to give 1.4 g (32% of theory) of N-(n-hexyl)-S-{3-[4-[4-(4-chlorophenyl)butyl]piperazin-1-yl]propyl}thiocarbamate dihydrochloride as a white crystalline solid, M.p. 235°-245° C. (dec.).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04722926uspto-grants-1988_02