反応 #3817

反応方程式

2,2'-dithiobisbenzoyl chloride

o-anisidine

→

title compound

収率 21.3%

2,2'-Dithiobis[N-(2-methoxyphenyl)benzamide]

収率 21.3%

溶媒

pyridine

dichloromethane

反応条件

後処理

1. 1
   その他This compound was prepared
2. 2
   その他The crude product was recrystallized from ethanol-ethyl acetate

実験手順

This compound was prepared according to the general method of Example 77 using 2,2'-dithiobisbenzoyl chloride (2.00 g, 5.83 mmol) in 50 mL of dichloromethane and o-anisidine (1.42 g, 11.5 mmol) in 10 mL of pyridine. The crude product was recrystallized from ethanol-ethyl acetate, then again from acetonitrile-DMF to yield 0.634 g of the title compound, mp 154°-155° C.

出典