反応 #354750

反応方程式

dimethyl-tert-butylchlorosilane

6-chlorohexan-1-ol

imidazole

→

6-chlorohexyloxy-dimethyl-tert-butylsilane

溶媒

dimethylformamide

反応条件

実験手順

To 33 g. of dimethyl-tert-butylchlorosilane in 100 ml. of dimethylformamide is added 27 g. of 6-chlorohexan-1-ol and 340 g. of imidazole. The reaction mixture is allowed to stand at room temperature for 3 days to yield 6-chlorohexyloxy-dimethyl-tert-butylsilane, which is worked up by pouring into water, extracting with ether, washing with water, drying over calcium sulfate, removing the solvent by evaporation and purifying by distillation.

出典