反応 #350559
ord-8bef3a7975ed42dc885d5b77b6c6816b
反応方程式
3-hydroxy hexanoic acid
(R)-3-hydroxyhexanoic acid
→
(S)-3-hydroxyhexanoic acid
反応条件
詳細条件
See reaction.notes.procedure_details.
後処理
- 1その他The reaction times
- 2その他The conversion of 20-80% is attained within the above preferable reaction times
実験手順
The reaction times are suitably 1 to 1000 hours, preferably 1 to 200 hours. Namely, the reaction time depends on the kind of the racemic esters of 3-hydroxy hexanoic acid which are starting materials. The conversion of 20-80% is attained within the above preferable reaction times. In this case, in the reaction of the conversion of 50% or less, (R)-3-hydroxyhexanoic acid having optical purity over 90% ee is obtained, while in the reaction of the conversion of 50% or more, (S)-3-hydroxyhexanoic acid having optical purity over 90% ee is obtained.