反応 #346398

ord-869234e2f04f418e8a5656bf746628e4

反応方程式

c1ccc(OP(c2ccccc2)c2ccccc2)cc1
phenyl diphenylphosphinite
CC=O
acetaldehyde
NS(=O)(=O)N1CCOCC1
morpholinosulfonylamine
→
CC(NS(=O)(=O)N1CCOCC1)P(=O)(c1ccccc1)c1ccccc1
Diphenyl[1-(morpholinosulfonylamino)ethyl]phosphine oxide

反応物

c1ccc(OP(c2ccccc2)c2ccccc2)cc1
phenyl diphenylphosphinite
CC=O
acetaldehyde
NS(=O)(=O)N1CCOCC1
morpholinosulfonylamine

試薬

なし

溶媒

Clc1ccccc1
chlorobenzene

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    workup.ADDITIONis treated by the procedure

実験手順

When a mixture of equimolar quantities of phenyl diphenylphosphinite, acetaldehyde, and morpholinosulfonylamine in chlorobenzene is treated by the procedure used in the preceding experiment, the product is a white solid, mp 215°-217° C., 31P nmr (DMSO-d6) -30.9 ppm.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04036913uspto-grants-1977_07