反応 #335342
ord-1b159444d1244d48bc290c258391c5e9
反応条件
詳細条件
See reaction.notes.procedure_details.
後処理
- 1その他the solvent is removed
- 2その他the residue evaporated with toluene several times
実験手順
To a moisture protected solution of 28.4 ml of phosphorous oxychloride in 200 ml of carbon tetrachloride is added dropwise with stirring a solution of 50 g of 1-hexadecanol in 125 ml of carbon tetrachloride. After stirring at ambient temperature for 18 hours, the solvent is removed and the residue evaporated with toluene several times to give 71 g of the desired product as a vacuum dried water white oil.