反応 #334895

ord-02a49089b68b4c768b9d92d5910ce35c

反応方程式

O=C1OCCO1
ethylene carbonate
CC(O)COC(C)CO
dipropylene glycol
O=C1OCCO1
ethylene carbonate
収率 100.0%
O=C=O
carbon dioxide
収率 14.7%

反応条件

温度
175°CELSIUS
詳細条件
See reaction.notes.procedure_details.

実験手順

A 10:1 mole ratio of ethylene carbonate to dipropylene glycol is heated with stirring under a nitrogen atmosphere for 4 hours at 175° C. using 0.5 percent sodium stannate trihydrate as catalyst to give 100 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 14.7 percent carbon dioxide The catalyst is removed as in Example 1.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04709069uspto-grants-1987_11