反応 #334893

ord-c5ec0c86aed749d4b5901138bf25d1f3

反応方程式

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
収率 98.0%
O=C=O
carbon dioxide
収率 10.8%

反応条件

温度
175°CELSIUS
詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    温度is heated

実験手順

A 10:1 mole ratio of ethylene carbonate to polyglycol P-425 is heated with stirring under a nitrogen atmosphere for 6 hours at 175° C. using 0.5 percent sodium stannate trihydrate as catalyst to give 98 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 10.8 percent carbon dioxide. The catalyst is removed as in Example 1.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04709069uspto-grants-1987_11