反応 #334887

ord-3d6694b4125645898566ca7e0ef4e948

反応方程式

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
収率 100.0%
O=C=O
carbon dioxide
収率 25.8%

反応条件

温度
135°CELSIUS
詳細条件
See reaction.notes.procedure_details.

実験手順

A 10:1 mole ratio of ethylene carbonate:monoethylene glycol is heated with stirring under a nitrogen atmosphere for 24 hours at 135° C. using 1.0 percent Na2SnO3.3H2O as catalyst to give a 100 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 25.8 percent carbon dioxide.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04709069uspto-grants-1987_11