反応 #334079
ord-6a1abf74018348e89a296be3483a4898
反応条件
詳細条件
See reaction.notes.procedure_details.
後処理
- 1その他As demonstrated by entries 4 and 5 in Table 1, at about 130° C.
実験手順
As demonstrated by entries 4 and 5 in Table 1, at about 130° C., the conversion of the three-carbon feedstock starting from acetone and hydrogen is 16.4% and from isopropanol is 8.6%. Isopropanol becomes the major reaction product, while MIBC predominates over MIBK in the aldol product. Small amounts of mesityl oxide are also seen, however, no diisobutylketone is formed. Thus, 130° C. favors secondary alcohols over ketones and the conversion of three-carbon feedstock to aldol products is poor.