反応 #319165
ord-6c338ea2cef04f129300214f89b16608
反応方程式
Tertiary butylamine
N-phosphonomethylglycine
N-t-butyl-N-phosphonomethylglycine
→
N-t-butylglycine
反応物
試薬
なし
反応条件
詳細条件
See reaction.notes.procedure_details.
実験手順
Gaertner, U.S. Pat. No. 3,927,080, describes the production of N-phosphonomethylglycine by acid-catalyzed dealkylation of N-t-butyl-N-phosphonomethylglycine or its esters. Tertiary butylamine is reacted with a bromoacetate ester to produce an ester of N-t-butylglycine which is in turn reacted with formaldehyde and phosphorous acid to produce the N-t-butyl-N-phosphonomethylglycine precursor.