反応 #302879

ord-480eeee1e94949eab8564a608a63afe1

反応方程式

[Cl-].[Cl-].[Mg+2]
magnesium chloride
C[CH2][K].O=C(O)CC(=O)O
ethyl potassium malonate
→
O=C([O-])CC(=O)[O-].[CH2]C.[Mg+2]
Ethyl Magnesium Malonate

反応物

[Cl-].[Cl-].[Mg+2]
magnesium chloride
C[CH2][K].O=C(O)CC(=O)O
ethyl potassium malonate

試薬

なし

溶媒

CC(C)O
isopropanol

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    ろ過After filtration, ethyl magnesium malonate
  2. 2
    その他was dried in vacuo

実験手順

To a stirred aqueous solution of 1.5 M magnesium chloride and 3 M ethyl potassium malonate was added five volumes of isopropanol. After filtration, ethyl magnesium malonate was dried in vacuo.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US08192952B2uspto-grants-2012_06