反応 #2686

反応方程式

n-Decylmagnesium bromide

n-Nonadecylmagnesium bromide

diethylcarbonate

HCl

n-Tetradecylmagnesium bromide

→

n-nonadecyl-n-tetradecyl-n-decylcarbinol

溶媒

ethyl ether

diethyl ether

反応条件

後処理

1. 1
   workup.ADDITIONis slowly added to the solution
2. 2
   workup.STIRRINGstirred for one hour at 30° C
3. 3
   乾燥The organic layer is dried with magnasium sulfate
4. 4
   その他the ethyl ether evaporated off

実験手順

n-Nonadecylmagnesium bromide (0.33 moles) in ethyl ether is slowly added to 0.33 mole of diethylcarbonate in 100 ml diethyl ether and stirred for one hour at 30° C. (nitrogen atmosphere). n-Tetradecylmagnesium bromide (0.33 mole) is slowly added to the solution and stirred for one hour at 30° C. n-Decylmagnesium bromide (0.33 mole) is slowly added to the solution and stirred for one hour at 30° C. The mixture is then slowly poured into 600 ml of a cold 10% HCl solution. The organic layer is dried with magnasium sulfate and the ethyl ether evaporated off to give n-nonadecyl-n-tetradecyl-n-decylcarbinol.

出典