反応 #2685

反応方程式

HCl

di-n-decyl-n-tetradecylcarbinol

calcium chloride

→

di-n-decyl-n-tetradecyl-methylchloride

溶媒

methylene chloride

反応条件

後処理

1. 1
   洗浄The product mixture is then washed with 1 liter of a 10% sodium carbonate solution
2. 2
   乾燥The organic layer is dried with magnesium sulfate
3. 3
   その他the methylene chloride is evaporated off

実験手順

One mole of di-n-decyl-n-tetradecylcarbinol is added to 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas is slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride is evaporated off to give di-n-decyl-n-tetradecyl-methylchloride.

出典