反応 #2680

反応方程式

HCl

tri-n-decylcarbinol

calcium chloride

→

tri-n-decylmethylchloride

収率 90.0%

溶媒

methylene chloride

反応条件

後処理

1. 1
   洗浄The product mixture is then washed with 1 liter of a 10% sodium carbonate solution
2. 2
   乾燥The organic layer is dried with magnesium sulfate
3. 3
   その他the methylene chloride evaporated off

実験手順

One mole of tri-n-decylcarbinol was added to a mixture of 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas was slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride evaporated off to give a 90% yield of tri-n-decylmethylchloride.

出典