反応 #2676

ord-3ce42197cace4f5dad3160cf94f08e0c

反応方程式

C=Cc1cc(OCOCCOC)c(OCOCCOC)c(Cl)c1Cl
alcohol
C=Cc1cc(OCOCCOC)c(OCOCCOC)c(Cl)c1Cl
2,3-dichloro-4,5bis-[(2-methoxyethoxy)-methoxy]-styrol
O=C(OO)c1cccc(Cl)c1
m-chloro perbenzoic acid
C=CC12C=C(OCOCCOC)C(OCOCCOC)=C(Cl)C1(Cl)O2
expected product
収率 99.6%
C=CC12C=C(OCOCCOC)C(OCOCCOC)=C(Cl)C1(Cl)O2
2,3-dichloro-4,5bis-[(2-methoxyethoxy)-methoxy]-(1,2-epoxy) styrol
収率 99.6%

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他were reacted

実験手順

Using the procedure of Stage D of Example 40, 13.2 g of thee allylic alcohol of Step C and 10.3 g of m-chloro perbenzoic acid were reacted to obtain 13.7 g of the expected product with a Rf=0.25 (AcOEt-cyclohexane 6-4).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05728828uspto-grants-1998_03