反応 #2538

ord-c16cf1c3e2df4892b6f3150e9b21bcaf

反応方程式

CSc1cccc(N)c1
3-methylthioaniline
O=C(O)c1cccc([N+](=O)[O-])c1
3-nitrobenzoic acid
CSc1cccc(NC(=O)c2cccc([N+](=O)[O-])c2)c1
title compound
収率 94.6%
CSc1cccc(NC(=O)c2cccc([N+](=O)[O-])c2)c1
3-Nitro-N-(3-methylthiophenyl)benzamide
収率 94.6%

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Using 3-methylthioaniline (2.1 ml, 16.5 mmol) and 3-nitrobenzoic acid (2.64 g, 15.0 mmol), the procedure of Reference Example 16 was repeated to obtain 4.09 g (94.6%) of the title compound in the form of light yellow needle crystals.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05728835uspto-grants-1998_03