反応 #2523

ord-bac4f35022814f6eaa0f9cad74b4ef8c

反応方程式

CSc1cccc(N)c1
3-methylthioaniline
O=C(O)c1ccc([N+](=O)[O-])cc1
4-nitrobenzoic acid
CSc1cccc(NC(=O)c2ccc([N+](=O)[O-])cc2)c1
title compound
収率 85.3%
CSc1cccc(NC(=O)c2ccc([N+](=O)[O-])cc2)c1
4-Nitro-N-(3-methylthiophenyl)benzamide
収率 85.3%

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Using 3-methylthioaniline (1.40 ml, 11.0 mmol) and 4-nitrobenzoic acid (1.67 g, 10.0 mmol), the procedure of Reference Example 16 was repeated to obtain 2.46 g (85.2%) of the title compound in the form of yellow powder.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05728835uspto-grants-1998_03