反応 #2487393

反応方程式

1,2-Dimethyl-1-propylpiperidinium bromide

lithium bis(trifluoromethanesulfonyl)imide

→

1,2-dimethyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide

収率 95.5%

溶媒

water

water

反応条件

後処理

1. 1
   その他was obtained immediately
2. 2
   抽出The obtained room-temperature ionic liquid was extracted with methylene chloride
3. 3
   洗浄washed with pure water six times
4. 4
   その他dried in vacuum at 100° C.

実験手順

1,2-Dimethyl-1-propylpiperidinium bromide (5.3 g, 22 mmol) and lithium bis(trifluoromethanesulfonyl)imide (7.09 g, 25 mmol) were mixed and stirred in pure water, so that a room-temperature ionic liquid which is insoluble in water was obtained immediately. The obtained room-temperature ionic liquid was extracted with methylene chloride and then washed with pure water six times and dried in vacuum at 100° C.; thus, 1,2-dimethyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide (9.37 g, 21 mmol) was obtained.

出典