反応 #2474

ord-796c9df1b95145c8a5bab3faf51eb692

反応方程式

CCCCC[C@H]1[C@@H](CC(=O)OC)CC[C@H]1O
methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate
→
CCCCC[C@H]1C(=O)CC[C@H]1CC(=O)OC
methyl (+)-cis-3-oxo-2-pentyl-1-cyclopentaneacetate

反応物

CCCCC[C@H]1[C@@H](CC(=O)OC)CC[C@H]1O
methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate

試薬

なし

溶媒

CO
methanol

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate, characterized by a [α]20D superior to +17° (c=1.795 g/ 100 ml, methanol).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US05728866uspto-grants-1998_03