反応 #2467923

反応方程式

9,10-bis(pentafluorophenyl)-9,10-dihydro-9,10-anthracenediol

potassium iodide

sodium hypophosphite

→

9,10-bis(pentafluorophenyl)anthracene

収率 39.2%

溶媒

acetic acid

反応条件

後処理

1. 1
   温度After cooling
2. 2
   ろ過white crystals were filtered off
3. 3
   その他The crude product was recrystallized
4. 4
   workup.ADDITIONa 1:1 mixture of toluene and hexane

実験手順

The reduction of the diol was accomplished by taking 5.44 g of 9,10-bis(pentafluorophenyl)-9,10-dihydro-9,10-anthracenediol in 50 mL of acetic acid and refluxing it with 9 g of potassium iodide and 9 g of sodium hypophosphite for 4 hours. After cooling, white crystals were filtered off. The crude product was recrystallized using a 1:1 mixture of toluene and hexane to yield 2.00 g of 9,10-bis(pentafluorophenyl)anthracene with a melting point of 337-338° C.

出典