反応 #2439933
ord-aab828bb22ad4223a4274e20cc3e925c
反応方程式
反応条件
後処理
- 1その他the mixture was reacted for 8 hours under an N2 atmosphere
- 2その他the product was precipitated from 1,000 ml diethyl ether
- 3その他dried in vacuum
実験手順
To a 250 ml round bottomed flask was added methacrylic acid (7 g), acrolein (33 g), azobisisobutyronitrile (AIBN) (0.8 g), and propylene glycol methyl ether acetate (90 g), and the mixture was reacted for 8 hours under an N2 atmosphere. When the reaction was complete, the product was precipitated from 1,000 ml diethyl ether, and then dried in vacuum to give poly(methacrylic acid/acrolein) (25 g). To another 250 ml round flask was added the obtained poly(methacrylic acid/acrolein) (25 g), p-toluene sulfonic acid (0.1 g), and methanol (70 g), and the mixture was reacted for 24 hours at 70 oC. When the reaction was complete, the product was precipitated from n-hexane to give the titled polymer (yield: 70%). FIG. 4 shows an NMR spectrum of the titled compound.