反応 #2348119

ord-34c1352e9bea46f589f39298dd19a28d

反応方程式

[Br-]
bromide
O=COc1ccccc1
Formic acid phenyl ester
O=Cc1ccccc1
benzaldehyde
O=C(OO)c1cccc(Cl)c1
m-CPBA
C(=Cc1ccccc1)c1ccccc1
stilbene

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他to form 7

実験手順

Formic acid phenyl ester 7 may be synthesized from the corresponding benzaldehyde via traditional oxidation methods known in the art. For example, Baeyer-Villiger oxidation using m-CPBA to form 7, followed by deformylation using a suitable base and exposure to bromide 8 affords stilbene analog 9.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07846915B2uspto-grants-2010_12