反応 #2316915

反応方程式

triphenylcyclopropenylium chloride

sodium hexafluoroantimonate

triphenylcyclopropenylium chloride

→

Triphenylcyclopropenylium hexafluoroantimonate

溶媒

CH3CN

acetonitrile

反応条件

後処理

1. 1
   その他NaCl was removed by filtration
2. 2
   洗浄washed with CH3CN
3. 3
   workup.ADDITIONTo the filtrate was added ether
4. 4
   ろ過After filtration
5. 5
   その他a white, very light yellow solid was obtained
6. 6
   その他was between about 319 and 321° C.

実験手順

Triphenylcyclopropenylium hexafluoroantimonate was synthesized by the metatheses of triphenylcyclopropenylium chloride with sodium hexafluoroantimonate in acetonitrile. 0.003 moles of the triphenylcyclopropenylium chloride (literature) of Example 1 and 0.0031 moles of SbF6 was each separately dissolved in 10 ml of CH3CN and then combined. NaCl was removed by filtration and washed with CH3CN. To the filtrate was added ether. After filtration, a white, very light yellow solid was obtained. The melting point of this solid was between about 319 and 321° C.

出典