反応 #2301656

ord-bb224be7caa84e35b927dd251fdb839a

反応方程式

$Cc1cc(C)c(/C=C2\C(=O)N(CO)c3ccccc32)[nH]1$

(3Z)-3-[(3,5-dimethyl-1H-pyrrol-2-yl)-methylidene]-1-(hydroxymethyl)-1,3-dihydro-2H-indol-2-one

dibenzyl phosphorochloridate

→

$Cc1cc(C)c(/C=C2\C(=O)N(COP(=O)(OCc3ccccc3)OCc3ccccc3)c3ccccc32)[nH]1$

title compound

$Cc1cc(C)c(/C=C2\C(=O)N(COP(=O)(OCc3ccccc3)OCc3ccccc3)c3ccccc32)[nH]1$

dibenzyl {(3Z)-3-[(3,5-dimethyl-1H-pyrrol-2-yl)methylidene]-2-oxo-2,3-dihydro-1H-indol-1-yl}methyl phosphate

反応物

$Cc1cc(C)c(/C=C2\C(=O)N(CO)c3ccccc32)[nH]1$

(3Z)-3-[(3,5-dimethyl-1H-pyrrol-2-yl)-methylidene]-1-(hydroxymethyl)-1,3-dihydro-2H-indol-2-one

dibenzyl phosphorochloridate

試薬

なし

反応条件

詳細条件

See reaction.notes.procedure_details.

実験手順

The title compound was prepared from (3Z)-3-[(3,5-dimethyl-1H-pyrrol-2-yl)-methylidene]-1-(hydroxymethyl)-1,3-dihydro-2H-indol-2-one and dibenzyl phosphorochloridate (modification of procedure used to prepare {3(Z)-3-[(3,5-dimethyl-1H-pyrrol-2-yl)-methylidene]-2-oxo-2,3-dihydro-1H-indol-1-yl}methyl acetate).

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07109185B2uspto-grants-2006_09