反応 #2298116

反応方程式

9,10-dichloromethylanthracene

2-dimethylaminoethylamine

→

title compound

収率 36.7%

9,10-bis-[N-(2-Dimethylaminoethyl)aminomethyl]anthracene

収率 36.7%

溶媒

water

反応条件

後処理

1. 1
   ろ過the precipitate collected by filtration
2. 2
   その他The dried solid is then recrystallised from ethyl acetate

実験手順

1.0 g (0.0036 mol) of 9,10-dichloromethylanthracene (0.0036 mol) is refluxed for 20 minutes with 15 g of 2-dimethylaminoethylamine. The reaction mixture is added to water and the precipitate collected by filtration. The dried solid is then recrystallised from ethyl acetate to yield 0.5 g of the title compound as yellow crystals, m.p. 58°-60° C.; λmax (distilled water) (E/cm/M) 248 nm (51760), 372 nm (9030), 392 nm (8305).

出典