反応 #2267055

反応方程式

pentafluorobenzenesulfonyl chloride

tetramethylammonium hydroxide

→

tetramethylammonium pentafluorobenzenesulfonate

溶媒

methanol

反応条件

後処理

1. 1
   温度cooling

実験手順

25 gof pentafluorobenzenesulfonyl chloride was dissolved in 100 ml of methanol under ice-cooling. Then 100 g of a 25% aqueous solution of tetramethylammonium hydroxide was slowly added thereto. By stirring at room temperature for 3 hours, a solution of tetramethylammonium pentafluorobenzenesulfonate was obtained. Thus solution was employed in salt exchange between sulfonium salt and iodonium salt.

出典