反応 #217455

反応方程式

hydrochloric acid

2-Acetyl-7-hydroxyfluorene

allyl(4-chlorobutyl) ether

potassium carbonate

→

2-acetyl-7-(allyloxybutyloxy)fluorene

収率 65.5%

溶媒

dimethylformamide

反応条件

後処理

1. 1
   その他to obtain a solid matter
2. 2
   ろ過The solid matter was filtered
3. 3
   その他dried
4. 4
   その他it was recrystallized from ethanol

実験手順

2-Acetyl-7-hydroxyfluorene 22.4 g, allyl(4-chlorobutyl) ether 18 g and potassium carbonate 20 g were added to dimethylformamide 150 ml and stirred at 90° C. for 8 hours. The reaction mixture was poured into 6N hydrochloric acid 300 ml to obtain a solid matter. The solid matter was filtered and dried, and then it was recrystallized from ethanol to obtain 22 g of 2-acetyl-7-(allyloxybutyloxy)fluorene. The melting point was 77° C.

出典