反応 #217446

ord-151c7be8b66d4c429fb8c3011d0ac2de

反応方程式

COC(=O)c1ccc(C(=O)OC)c(C(=O)O)c1
1,4-dicarbomethoxy-3-carboxy benzene
O=C(O)c1ccc(C(=O)O)c(C(=O)O)c1
trimellitic acid
O=C(O)c1ccc(C(=O)O)c(C(=O)Oc2ccccc2)c1
1,4-dicarboxy-3-carbophenoxy benzene
O=C(O)c1ccc(C(=O)O)c(C(=O)O)c1
trimellitic acid
CCN(CC)CC
triethylamine
O=C(O)c1ccc(C(=O)O)c(C(=O)O)c1
trimellitic acid
N
ammonia
CNC
dimethylamine

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

Example of the polyamide-imide powder includes a condensation product of trimellitic acid derivative and aromatic diamine. Example of the trimellitic acid derivative includes trimellitic anhydride; trimellitic anhydride monochloride; 1,4-dicarboxy-3-N,N-dimethyl carbamoyl benzene; 1,4-dicarbomethoxy-3-carboxy benzene; 1,4-dicarboxy-3-carbophenoxy benzene; and ammonium salts formed of trimellitic acid, ammonia, dimethylamine, triethylamine, etc. Among these, trimellitic anhydride, trimellitic anhydride monochloride, etc. are often used with preference. Example of the aromatic diamine includes 2,2-bis[4-(4-aminophenoxy)phenyl] propane; 2,2 bis[4-(4-aminophenoxy)phenyl] butane; 1,1-bis[4-(4-aminophenoxy)phenyl]cyclohexane; 1,1-bis[4-(4-aminophenoxy)phenyl]cyclopentane; bis[4-(4-aminophenoxy)phenyl]sulfone; bis[4-(4-aminophenoxy)phenyl]ether; 4,4′-carbonyl bis(P-phenylene oxy) dianiline, etc.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07381280B2uspto-grants-2008_06