反応 #216833

反応方程式

diphenyliodonium chloride

lithium tetrakis(pentafluorophenyl)borate

→

diphenyliodonium tetrakis(pentafluorophenyl)borate

収率 75.0%

溶媒

water

water

反応条件

後処理

1. 1
   温度The mixture was maintained
2. 2
   ろ過was then filtered
3. 3
   その他The filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light
4. 4
   その他16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered

実験手順

7.17 g (or 22.6 mmol) of diphenyliodonium chloride were dissolved in 300 ml of water in a 1,000 ml Erlenmeyer flask. 15.52 g (or 22.6 mmol) of lithium tetrakis(pentafluorophenyl)borate in solution in 250 ml of water were added dropwise. The mixture was maintained under stirring for 30 minutes and was then filtered. The filtrate was dried under reduced pressure (133 Pa) overnight with the exclusion of light. 16.33 g (or a yield of 75%) of diphenyliodonium tetrakis(pentafluorophenyl)borate were thus recovered.

出典