反応 #2161234

ord-eefe87d255cc40779d4d77ecc2be97f5

反応方程式

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl)sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene
CC(C)(C)c1ccc([S+](c2ccc(C(C)(C)C)cc2)c2ccc(C(C)(C)C)cc2)cc1.[Br-]
tris(4-tert-butylphenyl)sulfonium bromide

溶媒

反応条件

詳細条件
See reaction.notes.procedure_details.

後処理

  1. 1
    その他The target compound was obtained
  2. 2
    その他the procedure of Synthesis Example 1 aside
  3. 3
    その他in Synthesis Example 1
  4. 4
    抽出for extraction

実験手順

The target compound was obtained by following the procedure of Synthesis Example 1 aside from using bis(4-tert-butylphenyl)sulfoxide instead of the diphenyl sulfoxide and 4-tert-butylbromobenzene instead of the chlorobenzene in Synthesis Example 1, and increasing the amount of water for extraction.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US07919226B2uspto-grants-2011_04