反応 #214332

ord-9ef01ab0cce84d94a11b7daf1636847e

反応方程式

O=S(=O)(O)c1c(S(=O)(=O)O)c2[nH]c1cc1nc(cc3ccc(cc4nc(c2S(=O)(=O)O)C=C4)[nH]3)-c2ncccc2-1.[Ca]
tri sulfo pyrido porphine calcium
O=C([O-])C1=NN(c2ccc(S(=O)(=O)[O-])cc2)C(=O)C1N=Nc1ccc(S(=O)(=O)[O-])cc1.[Na+].[Na+].[Na+]
tri sodium salt
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
O=S(=O)(O)c1c(S(=O)(=O)O)c2[nH]c1cc1nc(cc3ccc(cc4nc(c2S(=O)(=O)O)C=C4)[nH]3)-c2ncccc2-1
tri sulfo pyrido porphine
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
→
O=S(=O)(O)c1c(S(=O)(=O)O)c2[nH]c1cc1nc(cc3ccc(cc4nc(c2S(=O)(=O)O)C=C4)[nH]3)-c2ncccc2-1.[NH4+].[NH4+].[NH4+]
Tri sulfo pyrido porphine, tri ammonium salt

反応物

O=S(=O)(O)c1c(S(=O)(=O)O)c2[nH]c1cc1nc(cc3ccc(cc4nc(c2S(=O)(=O)O)C=C4)[nH]3)-c2ncccc2-1.[Ca]
tri sulfo pyrido porphine calcium
—
disulfobenzo-meso-tetra(sulfo-4-pyridyl) porphine zinc
—
meso-disulfopyrryl-meso-disulfo phenyl porphine
O=C([O-])C1=NN(c2ccc(S(=O)(=O)[O-])cc2)C(=O)C1N=Nc1ccc(S(=O)(=O)[O-])cc1.[Na+].[Na+].[Na+]
tri sodium salt
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
—
hexa sodium
—
tri ammonium
—
meso-disulfopyrryl-meso-disulfo phenyl porphine
—
hexa sodium
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
—
1,2,3,4,5,6,7,8-octamethyl-meso-disulfopyrryl-meso-disulfo pheyl porphine, tetra ammonium salt
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
—
1,2,3,4,5,6,7,8-octa n-propyl -meso-disulfopyrryl-meso-disulfo phenyl porphine zinc
O=S(=O)(O)c1c(S(=O)(=O)O)c2[nH]c1cc1nc(cc3ccc(cc4nc(c2S(=O)(=O)O)C=C4)[nH]3)-c2ncccc2-1
tri sulfo pyrido porphine
—
disulfobenzo-meso-tetrasulfophenyl porphine
NC(=O)C1=CN(C2OC(COP(=O)([O-])OP(=O)([O-])OCC3OC(n4cnc5c(N)ncnc54)C(OP(=O)([O-])[O-])C3O)C(O)C2O)C=CC1.[Na+].[Na+].[Na+].[Na+]
tetra sodium
—
meso-disulfo-pyrryl-meso-disulfo phenyl porphine zinc

試薬

なし

反応条件

詳細条件
See reaction.notes.procedure_details.

実験手順

tri sulfo pyrido porphine calcium, tri ammonium salt; tri sulfo pyrido porphine, tri sodium salt; meso-disulfopyrryl-meso-disulfo phenyl porphine, tetra sodium salt; meso-disulfo-pyrryl-meso-disulfo phenyl porphine zinc, tetra sodium salt; meso-disulfopyrryl-meso-disulfo phenyl porphine, tetra sodium salt, 1,2,3,4,5,6,7,8-octamethyl-meso-disulfopyrryl-meso-disulfo pheyl porphine, tetra ammonium salt; 1,2,3,4,5,6,7,8-octa n-propyl -meso-disulfopyrryl-meso-disulfo phenyl porphine zinc, tetra sodium salt; disulfobenzo-meso-tetrasulfophenyl porphine, hexa sodium salt; disulfobenzo-meso-tetra(sulfo-4-pyridyl) porphine zinc, hexa sodium salt.

出典

DOI: 10.6084/m9.figshare.5104873.v1特許: US04255273uspto-grants-1981_03