反応 #2082

反応方程式

1,3-dibromopropane

triethyl phosphite

bromoethane

→

Diethyl 3-bromopropanephosphonate

反応条件

後処理

1. 1
   workup.DISTILLATIONdistilled over into a strongly ice-
2. 2
   温度cooled receiver
3. 3
   workup.DISTILLATIONThe reaction mixture was distilled first in a bulb tube

実験手順

A mixture of 605 g (3.0 mol) of 1,3-dibromopropane and 250 g (1.5 mol) of triethyl phosphite was heated at an oil bath temperature of 130° C., while stirring and passing in nitrogen, for approximately 5 hours until approximately 154 g (1.5 mol) of bromoethane distilled over into a strongly ice-cooled receiver. The reaction mixture was distilled first in a bulb tube and then fractionally.

出典